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Preparation and Characteristics of tetragonal phase zirconia using dolomite

机译:白云石制备四方相氧化锆及其特征

摘要

Tetragonal zirconia polycrystal ceramics were stabilized by three different type of dolomite (white, black, cream). The TZP powders were synthesized by co-precipiatation method using ZrOCl2 and 3,4,5,6mol% dolomite solution with HCl .The precipitated gel were washed to give soft agglomerate with higher green density. The powder exhibited the tetragonal phase at 850°C temperature due to their small crystallite size. The phase evolution was the function of calcinations temperature. The densification behaviour shows a higher shrinkage rate for the compacts with white dolomite stabilized. These powders were compacted by uniaxial pressing and fired at 1400 to 1600°C for 4hrs.The relative density was higher for white dolomite stabilized TZP as compared to the other two for all sintering temperature and also it will increasing with temperature. This also retained the metastable tetragonal phase. The observed sintered compacts show an isotropic shrinkage which explains the better density and high hardness and compressive strength (in case of black dolomite) even at higher temperature.
机译:四方氧化锆多晶陶瓷由三种不同类型的白云石(白色,黑色,奶油色)稳定。用ZrOCl2和3,4,5,6mol%白云石溶液与HCl共沉淀法合成TZP粉末,洗涤沉淀的凝胶得到高生坯密度的软团聚体。由于其微晶尺寸小,该粉末在850℃的温度下显示出四方相。相演化是煅烧温度的函数。对于白云石稳定的压坯,其致密化行为显示出较高的收缩率。这些粉末通过单轴压制压实并在1400至1600°C的温度下煅烧4小时。在所有烧结温度下,白色白云石稳定化TZP的相对密度均高于其他两种,并且会随着温度的升高而增加。这也保留了亚稳的四方相。观察到的烧结体显示出各向同性的收缩,这说明即使在较高温度下也具有更好的密度,较高的硬度和抗压强度(在黑色白云石的情况下)。

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    Singh Bipin;

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  • 年度 2007
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