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Entwicklung eines Direkt-Methanol-Brennstoffzellensystems der Leistungsklasse kleiner 5 kW

机译:开发性能等级低于5 kW的直接甲醇燃料电池系统

摘要

The attractiveness of electrical conversion of liquid methanol in a fuel cell is defined by its simple storage and high energy density. Therefore, direct methanol fuel cell (DMFC) qualifies for applications in portable systems and mobile application in the kW-class. The goal of this work is to develop and demonstrate an improved and optimized peripheral DMFC system compared to the current level of technology. The selected mobile application is the retrofit of the energy supply of a "Scooter" with a fuel cell system. The required size reduction and the simplification of the DMFC system are realized by an integrated concept, which combines ideally the peripheral system and the fuel cell. A profound analysis of the stack and the peripheral components is a prerequisite for an optimized design. A detailed modelling and understanding of the stack behaviour establish the starting point of this work. The influence of the most important operating parameters like stack temperature, cell voltage, current density, air ratio and methanol concentration is captured accurately by the developed model and validated by experimental data. This shapes the frame work of the following system design approach. For this the clearly defined task of the peripheral system are investigated individually for alternatives and the best option is selected for the final solution. For selecting the right pumps and blowers available products and prototypes are characterized and checked for the system requirements. The investigation and the modelling of the exhaust gas condenser lead to an optimized component design for the “Scooter” DMFC design. Additionally, the integration of the anode loop is accomplished consisting of the supply lines, the circulating pump, the gas separator and the exhaust line. The direct coupling of the fuel cell with a lithium-ion battery as an option for electrical conditioning is investigated. In the system modelling the influence of the operational parameter on characteristic performance indicators like electrical power, efficiency, and power density is analysed in combination with the heat and water management of the system. The system can be optimized only for single specific targets. For example the best system efficiency has been evaluated for a cell voltage of 400 mV and a stack temperature of 70°C. In the final part the development of the power supply of a Scooter is described. A compact system witha net power output of 1230 W has been realized. The system efficiency amounts up to 18.8%.
机译:燃料电池中液态甲醇电转化的吸引力取决于其简单的存储和高能量密度。因此,直接甲醇燃料电池(DMFC)符合kW级便携式系统和移动应用中的应用条件。这项工作的目的是开发和演示一种与当前技术水平相比经过改进和优化的外围DMFC系统。所选的移动应用是“踏板车”的能源供应与燃料电池系统的翻新。 DMFC系统所需的尺寸减小和简化是通过集成概念实现的,该概念理想地将外围系统和燃料电池结合在一起。对堆栈和外围组件进行深入分析是优化设计的前提。详细的建模和对堆栈行为的理解建立了这项工作的起点。通过开发的模型可以准确地捕获最重要的操作参数(如电池堆温度,电池电压,电流密度,空气比和甲醇浓度)的影响,并通过实验数据进行验证。这塑造了以下系统设计方法的框架。为此,将单独研究外围系统的明确定义的任务以寻找替代方案,并为最终解决方案选择最佳选择。为了选择合适的泵和鼓风机,对可用的产品和原型进行了表征,并检查了系统要求。对排气冷凝器的研究和建模导致了“ Scooter” DMFC设计的优化组件设计。另外,阳极回路的集成由供应管线,循环泵,气体分离器和排气管线组成。研究了燃料电池与锂离子电池的直接耦合作为电气调节的一种选择。在系统建模中,结合系统的热量和水管理,分析了运行参数对特征性能指标(如电功率,效率和功率密度)的影响。该系统只能针对单个特定目标进行优化。例如,对于电池电压为400 mV和电池组温度为70°C的最佳系统效率进行了评估。在最后一部分中,描述了踏板车电源的开发。已经实现了净输出功率为1230 W的紧凑型系统。系统效率高达18.8%。

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    Nölke Marcus;

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  • 年度 2007
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  • 原文格式 PDF
  • 正文语种 ger
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