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The electronic structure of sulfonamidyl radicals. An ESR spectroscopic and ab-initio MO study of sulfonamidyl and some carboxamidyl radicals

机译:磺酰胺基的电子结构。磺胺基和一些羧酰胺基的ESR光谱和从头算MO的研究

摘要

This thesis describes an investigation of the electronic structure of sulfonamidyl radicals (R1SO2NR2) and some structurally related carboxamidyl radicals (R1C(0)NR2). Both types of radicals have been invoked as intermediates in several chemical reactions. The present work originates from our interest in the influence of the sulfonyl group on a nitrogen-free radical center in comparison with that of the carbonyl group. ... Zie: Summary
机译:本文介绍了磺酰胺基(R1SO2NR2)和一些与结构相关的羧酰胺基(R1C(0)NR2)的电子结构的研究。在几种化学反应中,两种类型的自由基都被用作中间体。本工作源于我们对磺酰基与羰基相比对氮自由基中心的影响的兴趣。 ... Zie:摘要

著录项

  • 作者

    Teeninga Hermannus;

  • 作者单位
  • 年度 1983
  • 总页数
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类

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