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Exploratory studies on fast pyrolysis oil upgrading

机译:快速裂解油提质的探索性研究

摘要

Pyrolysis oil is a dark brown liquid which can be produced in high yield from different kind of biomass sources by means of fast pyrolysis. Pyrolysis oil is considered as a promising second generation energy carrier and may play an important role in the future of "biobased economies". The energy content of pyrolysis oil is approximately half of fossil crude. Just like for crude oil, further reprocessing is necessary to arranged pyrolysis oil as fuel in e.g. combustion engines. This thesis describes the results of exploratory research of pyrolysis oil upgrading for biofuel production. For that purpose two promising options have been examined. The first route includes the treatment of pyrolysis oil with hydrogen at elevated temperatures and presses in the presence of metal catalysts. It appears that the properties of oil improved considerably by using solid catalysts based on ruthenium. Moreover a mild treatment using homogeneous metal catalysts also shows a promising option. The Second part of the research has an objective on improving pyrolysis oil properties by mixing with alcohol as a reagent. It appears that reactive distillation using butanol leads to a considerable improvement of important product properties such as viscosity, acid quality and energy contents.
机译:热解油是一种深棕色液体,可以通过快速热解从不同种类的生物质来源中以高收率生产。热解油被认为是有前途的第二代能源载体,并可能在“生物基经济”的未来中发挥重要作用。热解油的能量含量约为化石原油的一半。就像原油一样,需要进一步的后处理以将热解油用作燃料,例如内燃机。本文描述了热解油提质用于生物燃料的探索性研究成果。为此,已经研究了两个有希望的选择。第一条途径包括在高温下用氢气处理热解油,并在金属催化剂存在下进行压制。看来通过使用基于钌的固体催化剂,油的性能得到了显着改善。此外,使用均相金属催化剂进行温和处理也显示出了有希望的选择。研究的第二部分的目标是通过与乙醇混合作为试剂来改善热解油的性能。看起来使用丁醇的反应蒸馏导致重要产品性能例如粘度,酸质量和能量含量的显着改善。

著录项

  • 作者

    Mahfud Farchad Husein;

  • 作者单位
  • 年度 2007
  • 总页数
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类

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