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Enantiomeric Excess Determination without Chiral Auxiliary Compounds. A New 31P NMR Method for Amino Acid Esters and Primary Amines

机译：没有手性辅助化合物的对映体过量测定。氨基酸酯和伯胺的31P NMR新方法

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Amino acid esters and primary amines yield diastereoisomeric methylphosphonic diamides 5 upon reaction with MePSCl2. The enantiomeric excess of amino acid esters and amines is easily determined by measurement of the ratio of diastereoisomers of 5 by 31P NMR spectroscopy.

机译：与MePSCl2反应后，氨基酸酯和伯胺可生成非对映异构体甲基膦酸二酰胺5。氨基酸酯和胺的对映体过量可以通过31 P NMR光谱法测量5的非对映异构体的比例来轻松确定。

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Strijtveen Bert; Kellogg Richard M.; Feringa Bernard;
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年度 1986
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正文语种 eng
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专利

1. A Chiral Phosphorous Derivatizing Agent for the Determination of the Enantiomeric Excess of Chiral Alcohols, Amines by 31p NMR [J] . 中国化学快报（英文版） . 2001,第010期

机译：31p NMR测定手性醇，胺的对映体过量的手性磷衍生剂
2. Determination of Enantiomeric Excess and Concentration of Unprotected Amino Acids,Amines,Amino Alcohols,and Carboxylic Acids by Competitive Binding Assays with a Chiral Scandium Complex [J] . Xuefeng Mei, Christian Wolf Journal of the American Chemical Society . 2006,第41期

机译：通过手性Scan配合物的竞争结合分析测定对映体过量和未保护的氨基酸，胺，氨基醇和羧酸的浓度
3. Discrimination and Enantiomeric Excess Determination of Chiral Primary Amines Based on a Chiral-at-Metal Ir(III) Complex Using NMR Spectroscopy [J] . Li Li-Ping, Ye Bao-Hui Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2017,第17期

机译：基于手性 - 金属IR（III）复合物的鉴别和对映体过量测定使用NMR光谱法
4. A NEW CHIRAL PHOSPHOROUS AGENT FOR THE DETERMINATION OF THE ENANTIOMERIC EXCESS OF CHIRAL ALCOHOLS,AMINES BY MEANS OF 31p NMR [C] . Li Kangying International symposium for Chinese organic chemists . 2000

机译：一种新的手性磷剂，用于测定对映体过量的手性醇，胺含31P NMR的胺
5. Detection of amino acids and their enantiomeric ratios in various samples, and the development of a new stationary phase for the chiral separation of amino acids. [D] . Kullman, John Peter. 2000

机译：检测各种样品中的氨基酸及其对映体比率，并开发用于氨基酸手性分离的新固定相。
6. A Facile CD Protocol for Rapid Determination of Enantiomeric Excess and Concentration of Chiral Primary Amines [O] . Sonia Nieto, Justin M. Dragna, Eric V. Anslyn -1

机译：用于快速测定对映体过量的容易CD方案小胺浓度
7. Enantiomeric Excess Determination without Chiral Auxiliary Compounds. A New 31P NMR Method for Amino Acid Esters and Primary Amines [O] . Strijtveen, Bert, Kellogg, Richard M., Feringa, Bernard 1986

机译：没有手性辅助化合物的对映体过量测定。氨基酸酯和伯胺的31P NMR新方法

Enantiomeric Excess Determination without Chiral Auxiliary Compounds. A New 31P NMR Method for Amino Acid Esters and Primary Amines

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