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Selective detection of dopamine using glassy carbon electrode modified by a combined electropolymerized permselective film of polytyramine and polypyrrole-1-propionic acid

机译:使用由聚酪胺和聚吡咯-1-丙酸组成的电聚合渗透选择膜修饰的玻璃碳电极选择性检测多巴胺

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摘要

A sensitive and selective electrochemical method for the determination of dopamine using a combined electropolymerized permselective film of polytyramine and polypyrrole-1-propionic acid on a glassy carbon (GC) electrode was developed. The formation of a u201clayer-by-layeru201d film has allowed for selective detection of dopamine in the presence of 3,4-dihydroxyphenylalanine (L-DOPA), DOPAC, ascorbic acid, uric acid, epinephrine and norepinephrine. The modified electrodes exhibited a detection limit of 100 nM with linearity ranging from 5 x 10u207bu2076 to 5 x 10u207bu2075 M. No cleaning step was required during the course of repeated measurement.
机译:开发了一种灵敏且选择性的电化学方法,通过在玻璃碳(GC)电极上使用聚酪胺和聚吡咯-1-丙酸的电聚合选择性渗透膜对多巴胺进行测定。逐层膜的形成允许在3,4-二羟基苯丙氨酸(L-DOPA),DOPAC,抗坏血酸,尿酸,肾上腺素和去甲肾上腺素的存在下选择性检测多巴胺。修饰的电极表现出100 nM的检测极限,线性范围为5 x 10 u207b u2076至5 x 10 u207b u2075M。在重复测量过程中,无需清洁步骤。

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