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The influence of rice husk ash addition on the properties of metakaolin-based geopolymers

机译:稻壳灰添加量对偏高岭土基聚合物性能的影响

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摘要

This paper investigates the replacement of metakaolin (MK) with rice husk ash (RHA) in the production of alkali-activated binders or geopolymers. The influence of the RHA addition on compressive and flexural strength, as well as water absorption and apparent porosity were determined, in terms of the percentage of RHA in the mixture and molar ratios of the mixes. Fourier Transform Infrared (FTIR) spectroscopy and Energy Dispersive spectroscopy (EDS) were carried out to assess the changes in the microstructure of the geopolymer matrices with the RHA addition. Results have shown that RHA may be a supplementary precursor for geopolymers. The composition of the geopolymer matrices containing 0-40% RHA is very similar, which indicates that the additional Si provided by RHA is not incorporated to the geopolymer matrix. In addition, geopolymers with RHA content higher than 40% present a plastic behavior, characterized by extremely low strength and high deformation, which can be attributed to the formation of silica gel in formulations containing variable Si/Al ratio.
机译:本文研究了用稻壳灰(RHA)代替偏高岭土(MK)来生产碱活化的粘合剂或地质聚合物。根据混合物中RHA的百分比和混合物的摩尔比,确定了RHA的添加对抗压强度和抗弯强度以及吸水率和表观孔隙率的影响。进行了傅里叶变换红外(FTIR)光谱和能量分散光谱(EDS),以评估添加RHA的地聚合物基质的微观结构的变化。结果表明,RHA可能是地质聚合物的补充前体。含有0-40%RHA的地质聚合物基质的组成非常相似,这表明RHA提供的其他Si没有掺入到地质聚合物基质中。此外,RHA含量高于40%的地质聚合物表现出塑性行为,其特征在于极低的强度和高变形,这可归因于在含可变Si / Al比的配方中形成了硅胶。

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