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Development of One Meter Long Double-Sided CeO2 Buffered Ni-5at.W Templates by Reel-to-Reel Chemical Solution Deposition Route

机译:卷到卷化学溶液沉积路线开发一米长的CeO2双面缓冲Ni-5at.W模板

摘要

High performance long-length coated conductors fabricated using various techniques have attracted a lot of interest recently. In this work, a reel-to-reel design for depositing double-sided coatings on long-length flexible metallic tapes via a chemical solution method is proposed and realized. The major achievement of the design is to combine the dip coating and drying processes in order to overcome the technical difficulties of dealing with the wet films on both sides of the tape. We report the successful application of the design to fabricate a one-meter-long double side coated CeO2/Ni-5at%W template. The CeO2 films on both sides exhibit a dense, crack-free morphology, and a high fraction of cube texture on the surface. Homogeneity studies on global texture over the length also reveal that the average full width at half maximum values of the in-plane and out-of-plane orientation on the CeO2 layer are 7.2 ° and 5.8° with standard deviation of 0.26° and 0.34°, respectively, being indicative of the high quality epitaxial growth of the films prepared in the continuous manner. An all chemical solution derived YBCOLow-TFA/Ce0.9La0.1O2 /Gd2Zr2O7/CeO2 structure is obtained on a short sample, demonstrating the possibility of producing long-length texture templates for coated conductors by this low cost deposition route.
机译:近来,使用各种技术制造的高性能长型涂覆导体引起了人们的极大兴趣。在这项工作中,提出并实现了一种通过化学溶液方法在长条柔性金属带上沉积双面涂层的卷到卷设计。设计的主要成就是将浸涂和干燥工艺相结合,以克服处理胶带两面湿膜的技术难题。我们报道了该设计在制造一米长的双面涂覆CeO2 / Ni-5at%W模板方面的成功应用。两侧的CeO2膜均表现出致密,无裂纹的形态,并且表面上的立方晶体结构比例很高。对整个长度上的整体纹理的同质性研究还显示,CeO2层的面内和面外取向的半峰平均全宽分别为7.2°和5.8°,标准偏差为0.26°和0.34°分别表示以连续方式制备的膜的高质量外延生长。在较短的样品上即可获得全化学溶液衍生的YBCOLow-TFA / Ce0.9La0.1O2 / Gd2Zr2O7 / CeO2结构,这表明可以通过这种低成本的沉积途径生产用于涂覆导体的长纹理模板。

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