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Combustion characteristics of Turkish hazelnut shell biomass, lignite coal and their respective blends via thermogravimetric analysis

机译:热重分析法分析土耳其榛子壳生物质,褐煤及其混合物的燃烧特性

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摘要

Thermal behavior and combustion kinetic of coal, hazelnut shell, andudcoal/hazelnut shell blends at the proper ratio were investigated withudthermogravimetric analysis (TG). Four mass ratios (20, 30, 40, 50 mass %) ofudcoal/biomass blends were prepared and oxidized under dynamic conditions fromudtemperature 298 to 1173 K at different heating rates. TG analysis indicated that the combustion of blended samples divided into two stages namely devolatilization and char oxidation combined with coal combustion step. The influence of biomass blends on thermal and kinetic behavior of coal was studied under non-isothermal conditions. It was found that the thermal degradation temperature of coal was higher than that of blended samples due to the molecular structure strength. Ozawa–Flynn–Wall model was applied to deal with non-isothermal TG data for the evaluation of the activation energy corresponding to the combustions of coal, hazelnut shell, and coal/hazelnutudshell blends. The average activation energy changed in the range of 90.9–215.3 kJ mol-1, respectively, depending on blending ratio.
机译:用热重分析(TG)研究了适当比例的煤,榛子壳和 udcoal /榛子壳混合物的热行为和燃烧动力学。制备四种质量比(20、30、40、50质量%)的 udcoal /生物质共混物,并在动态条件下(从298至1173 K的高温)以不同的加热速率氧化。 TG分析表明,混合样品的燃烧分为脱挥发分和焦炭氧化结合煤燃烧两个阶段。在非等温条件下研究了生物质共混物对煤的热力学和动力学行为的影响。发现由于分子结构强度,煤的热降解温度高于混合样品的热降解温度。使用Ozawa–Flynn–Wall模型处理非等温TG数据,以评估与煤,榛子壳和煤/榛子/壳混合气燃烧对应的活化能。平均活化能在90.9–215.3 kJ mol-1范围内变化,具体取决于混合比例。

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