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Preparation, Characterization and Catalytic Activity of Gold Nanoparticles Stabilized by Hydrophilic Polymers

机译:亲水性聚合物稳定的金纳米粒子的制备,表征和催化活性

摘要

Optical properties, structure, size and morphology of colloidal gold nanoparticles (AuNPs) stabilized by uda series of hydrophilic polymers possessing nonionic, anionic, cationic and amphoteric nature were characterized by visible spectroscopy, dynamic light scattering (DLS), X-ray diffraction (XRD) and scanning electron microscopy (SEM), transmission electron microscopy (TEM). The polymer-protected AuNPs were prepared by “one-pot” synthetic protocol. The kinetics of formation of AuNPs was determined. The influence of udthe molecular weight (Mw) of polymers and concentration of AuNPs on the size of AuNPs was shown. The udcatalytic activity of polymer-protected AuNPs with respect to hydrogenation of 4-nitrophenol was studied. udHigh conversion degree of 4-nitrophenol to 4-aminophenol was evaluated by visible spectroscopy.When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35034
机译:用可见光谱,动态光散射(DLS),X射线衍射( XRD)和扫描电子显微镜(SEM),透射电子显微镜(TEM)。通过“一锅法”合成方案制备聚合物保护的AuNP。测定了形成AuNP的动力学。显示了聚合物的分子量(Mw)和AuNPs的浓度对AuNPs尺寸的影响。研究了聚合物保护的AuNPs对4-硝基苯酚氢化的催化活性。 ud通过可见光谱法评估了4-硝基苯酚向4-氨基苯酚的高转化率。引用本文时,请使用以下链接http://essuir.sumdu.edu.ua/handle/123456789/35034

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