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Reversible Hydrogen Storage in Electrospun Composite Nanofibers

机译:电纺复合纳米纤维中的可逆储氢

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摘要

Composite nanofibers containing single-walled carbon nanotubes (SWNT) were prepared by using elec-trospinning technique and hydrogen adsorption/desorption isotherms were carried out by a Sieverts appa-ratus at room temperature. The SEM analysis of the nanofibers revealed that the deformation of the nano-fiber increases with increasing SWNT concentration. The diameter of neat nanofibers was below 200 nm and had smooth surface. The surface of the composite nanofibers was rough even by adding low quantity of SWNT. The hydrogen storage results showed an improvement in the adsorption capacity with increasing the SWNT content in composite nanofibers. These nanofibers were evacuated again to remove the ad-sorbed hydrogen at room temperature. Moreover, even though specific surface area and total pore volume were important factors for increasing the capacity of hydrogen adsorption. Finally, maximum adsorption capacity was 0.29 wt % in case of nanofibers with 10 wt % SWNT under 30 bar at 298 K.When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35201
机译:采用静电纺丝技术制备了含有单壁碳纳米管(SWNT)的复合纳米纤维,并通过Sieverts装置在室温下进行了氢吸附/脱附等温线。纳米纤维的SEM分析显示,纳米纤维的变形随着SWNT浓度的增加而增加。纯净纳米纤维的直径小于200 nm,表面光滑。即使添加少量的SWNT,复合纳米纤维的表面也是粗糙的。储氢结果显示,随着复合纳米纤维中SWNT含量的增加,吸附能力得到改善。再次抽空这些纳米纤维以在室温下除去吸附的氢。而且,即使比表面积和总孔体积是增加氢吸附能力的重要因素。最后,在298 K,30 bar下,10wt%SWNT的纳米纤维的情况下,最大吸附容量为0.29 wt%。引用本文时,请使用以下链接http://essuir.sumdu.edu.ua/handle/ 123456789/35201

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