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Nanostructured Films of Semiconducting Molybdenum Disulfide Obtained Through Exfoliation-Restacking Method

机译:剥落-堆积法获得的半导体二硫化钼纳米结构薄膜

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摘要

Preparing MoS2 films in mild conditions, using deposition of suspended MoS2 nanoplatelets onto the substrate is described. For this purpose, the nanosized MoS2 particles were obtained via restacking of MoS2 single layers produced by chemical exfoliation of bulk MoS2 crystals in liquid media. X-Ray diffraction study of the films showed that the basal planes of MoS2 crystallites are mainly oriented in the plane paral-lel to the substrate. Atomic force microscopy examination revealed the dependence of the film surface to-pography, as well as the roughness characteristics on the film thickness, which varied in the range of 0.03-2.2 m. Optical absorption spectra of the obtained MoS2 films were found to contain the same absorption bands as the spectra of thin natural MoS2 single crystals. Dark conductivity of the films was determined to be ~ 10–3 S∙сm–1 at 300 K. The present MoS2 films were found to be photosensitive in the range of 300-800 nm, providing the maximum value of photocurrent under photoexcitation at ~ 440 nm.When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35055
机译:描述了在温和条件下使用悬浮的MoS2纳米片沉积到基底上制备MoS2膜的方法。为此,通过将堆积的MoS2晶体在液体介质中化学剥离而产生的MoS2单层重新堆叠,获得了纳米级的MoS2颗粒。薄膜的X射线衍射研究表明,MoS2晶体的基面主要在与衬底平行的面内取向。原子力显微镜检查显示了薄膜表面成像的依赖性,以及粗糙度对薄膜厚度的影响,其变化范围为0.03-2.2微米。发现获得的MoS 2膜的光吸收光谱包含与薄天然MoS 2单晶的光谱相同的吸收带。薄膜的暗电导率在300 K下确定为〜10–3 S∙сm–1。发现目前的MoS2薄膜在300-800 nm范围内具有光敏性,从而提供了在〜的光激发下光电流的最大值。 440 nm。引用文档时,请使用以下链接http://essuir.sumdu.edu.ua/handle/123456789/35055

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