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Influence of Thermal Factor and Radiation Processing on the Structure and Stress State of TiC-WC System Ion-plasma Coatings

机译:热因子和辐射工艺对TiC-WC系统离子等离子体涂层结构和应力状态的影响

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摘要

The deposition temperature and proton radiation influence on the structure and stress-strain state of Ti‑W‑C system ion-plasma coatings was studied by the methods of wide-angle X-ray diffractometry combined with tensometry. It is found out that during sputtering MeC targets (where Me is a solid solution in the lattice of Ti and W atoms) when the ratio Ti / W reduces the transition from the one-phase state from (Ti, W)C carbide to the two-phase state takes place where the second one is represented by the lower in carbon a‑W2C‑phase. Formation of lower phases correlates with depleting the composition by the interstitial element (C) while the content of W in the coating increases that has a relatively small heat of the carbide formation value. Essential changes under irradiation with protons of 200 keV to dose of 6.5×1017 cm-2 occur only in a stress-strain state.
机译:采用广角X射线衍射法结合张力法研究了沉积温度和质子辐射对Ti‑W‑C体系离子等离子体涂层结构和应力应变状态的影响。发现在溅射MeC靶(其中Me是Ti和W原子的晶格中的固溶体)时,Ti / W的比例降低了从(Ti,W)C碳化物向单相态转变为碳化物的过程。两相状态发生,其中第二相由碳a-W2C相中较低的碳表示。较低相的形成与间隙元素(C)耗尽组成有关,而涂层中的W含量增加,碳化物形成值的热量相对较小。在200 keV的质子辐照下,剂量为6.5×1017 cm-2的本质变化仅在应力应变状态下发生。

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