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Nanostructure Zinc Oxide with Cobalt Dopant by PLD for Gas Sensor Applications

机译:PLD的钴掺杂剂纳米结构氧化锌在气体传感器中的应用

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摘要

The present paper is based on study of polycrystalline ZnO:Co thin films deposited on glass substrates by pulsed laser deposition (PLD) technique using pulsed Nd-YAG laser with wavelength ( = 532 nm) and duration (7 ns) and energy fluence (1.4 J/cm 2) with different doping (1 wt. %, 3 wt. % and 5 wt. %). The X-Ray diffraction patterns of the films showed that the ZnO films and ZnO:Co films exhibit wurtzite crystal structure and high crystalline quality. The root mean square (RMS) surface roughness of Co doped ZnO thin films was estimated using atomic force microscopy (AFM) found to be 50.95 nm, 55.78 nm, 56.94 nm and 67.88 nm for pure,1 wt. %, 3 wt. % and 5 wt. % Co doping concentrations respectively. Through the electrical properties, electrical D.C conductivity at temperature range (27-300) ºC for ZnO:Co films as studied which are realized that these films have two activation energies. Hall effect is studied to estimate the type of carriers, from the result we deduced that the ZnO:Co thin films are n-type. The films exhibited good sensitivity to the ethanol vapors with quick response-recovery characteristics and it was found that the sensitivity for detecting (80) ppm, for ethanol vapor was of (27.5), (31.75), (79.0) and (53.1) at an operating temperature of (50) C for ZnO:Co thin films.When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/27778
机译:本文是基于对使用脉冲Nd-YAG激光的脉冲激光沉积(PLD)技术在玻璃基板上沉积的多晶ZnO:Co薄膜的研究,该激光的波长(= 532 nm),持续时间(7 ns)和能量通量( 1.4J / cm 2)具有不同的掺杂(1重量%,3重量%和5重量%)。薄膜的X射线衍射图表明,ZnO薄膜和ZnO:Co薄膜具有纤锌矿晶体结构和高结晶质量。使用原子力显微镜(AFM)估算Co掺杂的ZnO薄膜的均方根(RMS)表面粗糙度,发现纯净重量为1 wt。%时分别为50.95 nm,55.78 nm,56.94 nm和67.88 nm。 %,3重量%和5 wt。 Co掺杂浓度分别%。通过电学性质,对所研究的ZnO:Co薄膜在(27-300)ºC温度范围内的直流电导率进行了研究,发现这些薄膜具有两种活化能。通过研究霍尔效应来估计载流子的类型,我们得出的结果是ZnO:Co薄膜为n型。该膜对乙醇蒸气表现出良好的灵敏度,并具有快速的响应恢复特性,并且发现对于乙醇蒸气,检测(80)ppm的灵敏度为(27.5),(31.75),(79.0)和(53.1)。 ZnO:Co薄膜的工作温度为(50)°C。引用本文时,请使用以下链接http://essuir.sumdu.edu.ua/handle/123456789/27778

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