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Orientation Characteristics of Non-regiocontrolled Poly (3-hexyl-thiophene) Film by FTM on Various Liquid Substrates

机译:FTM在各种液体基质上非区域控制的聚(3-己基噻吩)薄膜的取向特性

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摘要

Orientation characteristics of non-regiocontrolled poly (3-hexylthiophene) (NR-P3HT) films prepared by dynamic casting of floating film and transferring method (FTM) has been investigated. The film was first cast on liquid-substrate to obtain as a floating-film followed by its transfer on solid-substrate such as white-glass or Si-wafer in order to evaluate their optoelectronic characteristics. As a possible key-factor to generate the orientation of conjugated polymer in this method we focused on the components of liquid-substrate in this study. The orientation dependence upon various liquid-substrates reveals that dichroic ratio strongly changes with liquid-substrates. Pictures of floating-film show the change in size of floating-parts depending upon the liquid-substrate, representing the expansion length of casting solution upon the viscosity. These findings have indicated that spreading speed of polymer solution and solvent evaporation speed controls the size of floating-film leading to change in the orientation intensity. The multilayer coatings of oriented NR-P3HT films were used for polarized FTIR analysis exhibiting clear dichroism. The obtained dichroic characteristics were well corresponded with in-plane, out-of-plane and non-oriented vibronic modes of P3HT.
机译:研究了通过动态流延浮膜和转移方法(FTM)制备的非区域控制的聚(3-己基噻吩)(NR-P3HT)膜的取向特性。首先将膜浇铸在液体基质上,以得到浮膜,然后将其转移到诸如白玻璃或硅晶圆的固体基质上,以评估其光电特性。作为此方法中产生共轭聚合物取向的可能关键因素,我们在本研究中重点研究了液体基质的成分。对各种液体基质的取向依赖性表明,二向色比随液体基质强烈变化。浮膜图片显示了浮体尺寸的变化,取决于液体基质,代表了流延溶液在粘度上的膨胀长度。这些发现表明,聚合物溶液的扩散速度和溶剂蒸发速度控制着浮膜的尺寸,从而导致取向强度的改变。取向NR-P3HT薄膜的多层涂层用于偏振FTIR分析,显示出清晰的二向色性。所获得的二向色特性与P3HT的面内,面外和非定向振动模式非常吻合。

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