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Electrochemical synthesis of CORE-shell magnetic nanowires

机译:核壳磁性纳米线的电化学合成

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摘要

(Fe, Ni, CoFe) @ Au core-shell magnetic nanowires have been synthesized by optimized two-step potentiostatic electrodeposition inside self-assembled nanopores of anodic aluminium templates. The optimal electrochemical parameters (e.g., potential) have been firstly determined for the growth of continuous Au nanotubes at the inner wall of pores. Then, a magnetic core was synthesized inside the Au shells under suitable electrochemical conditions for a wide spectrum of single elements and alloy compositions (e.g., Fe, Ni and CoFe alloys). Novel opportunities offered by such nanowires are discussed particularly the magnetic behavior of (Fe, Ni, CoFe) @ Au core-shell nanowires was tested and compared with that of bare TM nanowires. These core-shell nanowires can be released from the template so, opening novel opportunities for biofunctionalization of individual nanowires.
机译:(Fe,Ni,CoFe)@ Au核壳磁性纳米线是通过在阳极铝模板的自组装纳米孔内优化的两步恒电位电沉积法合成的。首先为孔内壁连续金纳米管的生长确定了最佳的电化学参数(例如电势)。然后,在合适的电化学条件下,在Au壳内合成了磁芯,以用于宽范围的单一元素和合金成分(例如,Fe,Ni和CoFe合金)。特别讨论了由此类纳米线提供的新颖机会,并测试了(Fe,Ni,CoFe)Au核壳纳米线的磁行为并将其与裸TM纳米线的磁行为进行了比较。这些核-壳纳米线可以从模板中释放出来,从而为单个纳米线的生物功能化打开了新的机会。

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