Modification des propriétés aux interfaces d'homopolymères par des copolymères fluorés

摘要

The study of the interfacial properties of the polymer systems brought to us to synthesize anionic alive polymerization, radical polymerization model systems of polymers and fluoride copolymers. The study of the interfacial behavior required various techniques (S.I.M.S ., I.SS., XPS.).The conclusion major of our work is the highlighting of two competitive phenomena, the distribution of the copolymer fluorinated towards a polar substratum and a degradation of the chains of polymers.