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Reductive Hydrazination with Trichlorosilane: A Method for the Preparation of 1,1-Disubstituted Hydrazines

机译：三氯硅烷的还原水合反应：一种制备1,1-二取代肼的方法

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A straightforward and facile method has been developed to prepare 1,1-disubstituted hydrazines via Lewis base promoted direct reductive hydrazination. Under the catalysis of hexamethylphosphoramide (HMPA) and N,N-dimethylacetamide (DMAc), respectively, various ketones and aldehydes could react with phenylhdrazines to prepare 1,1-disubstituted hydrazines with good to high yields.

机译：已经开发了一种简单易行的方法，以通过路易斯碱促进的直接还原酰肼化来制备1,1-二取代的肼。分别在六甲基磷酰胺（HMPA）和N，N-二甲基乙酰胺（DMAc）的催化下，各种酮和醛可与苯基乙嗪反应制备1,1-二取代肼，产率高至高。

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Wang T; Di X; Wang C; Zhou L; Sun J;
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1. Reductive Hydrazination with Trichlorosilane: A Method for the Preparation of 1,1-Disubstituted Hydrazines [J] . Wang Tao, Di Xiao, Wang Chao, Organic letters . 2016,第8期

机译：三氯硅烷的还原水合反应：一种制备1,1-二取代肼的方法
2. Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclohexa-l,3-diene with Trichlorosilane by Use of Chiral Phosphoramidite Ligands from 3,3'-Disubstituted 1,1'-Binaphthols [J] . Hyun-Sub Park, Hye Mi Shin, Suk Namgung Bulletin of the Korean Chemical Society . 2014,第9期

机译：通过3,3'-双取代的1,1'-双萘酚的手性亚磷酰胺配体，钯催化环六-1,3-二烯与三氯硅烷的不对称氢化硅烷化
3. A novel route to unsymmetrical disubstituted ureas and thioureas by HMPA catalyzed reductive alkylation with trichlorosilane [J] . Organic Chemistry Frontiers . 2020,第3期

机译：通过HMPA催化与三氯硅烷催化还原烷基化的一种新型途径
4. Preparation of Fe-Ni/C Composite Catalyst for the Hydrazine Hydrate Catalytic Reduction [C] . Jinhua Zhou, Hanzhou Sun, Haili Gao, International conference on biotechnology, chemical and materials engineering . 2013

机译：用于水合肼催化还原的Fe-Ni / C复合催化剂的制备
5. Development of new chemistry for a dual use hydrazine thruster switchable room temperature ionic liquids a study of silane grafting to model polyethylene compounds synthesis of the novel hydrazine replacement fuel molecules 1,1-dimethyl-2-[2-azidoethyl]hydrazine and 1,1-dimethyl-2-[2-azidoethyl]hydrazone . [D] . Huttenhower, Hilary Anne. 2010

机译：两用肼推进器可切换室温离子液体的新化学研究进展，研究硅烷接枝模拟聚乙烯化合物合成新型肼替代燃料分子1,1-二甲基-2- [2-叠氮基乙基]肼和1,1的研究-二甲基-2- [2-叠氮基乙基] hydr。
6. Ultrasound-Assisted Hydrazine Reduction Method for the Preparation of Nickel Nanoparticles Physicochemical Characterization and Catalytic Application in Suzuki-Miyaura Cross-Coupling Reaction [O] . Adél Anna Ádám, Márton Szabados, Gábor Varga, 2020

机译：超声辅助肼还原法制备镍纳米粒子的理化表征及其在铃木宫浦交叉偶联反应中的催化应用
7. Ultrasound-Assisted Hydrazine Reduction Method for the Preparation of Nickel Nanoparticles, Physicochemical Characterization and Catalytic Application in Suzuki-Miyaura Cross-Coupling Reaction [O] . Adél Anna Ádám, Márton Szabados, Gábor Varga, 2020

机译：超声辅助肼还原方法，用于制备镍纳米粒子，物理化学表征和苏苏宫瘤交叉偶联反应的催化应用
8. Oxidative Reactions of Hydrazines Ⅴ Synthesis of 1, 1- Disubstituted Hydrazines and their Sulfonyl Derivatives [R] . Louis A. Carpino, A. A. Santilli 1959

机译：肼的氧化反应Ⅴ1,1-二取代肼及其磺酰基衍生物的合成

Reductive Hydrazination with Trichlorosilane: A Method for the Preparation of 1,1-Disubstituted Hydrazines

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