首页> 外文OA文献 >Catalytic H/D exchange between organic compounds and D2O with TpRu(PPh3)(CH3CN)H (Tp = hydro(trispyrazolyl)borate). Reaction of TpRu(PPh3)(CH3CN)H with water to form acetamido complex TpRu(PPh3)(H2O)(NHC(O)CH3)

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Catalytic H/D exchange between organic compounds and D2O with TpRu(PPh3)(CH3CN)H (Tp = hydro(trispyrazolyl)borate). Reaction of TpRu(PPh3)(CH3CN)H with water to form acetamido complex TpRu(PPh3)(H2O)(NHC(O)CH3)

机译：用TpRu（PPh3）（CH3CN）H（Tp =氢（三吡唑基）硼酸酯）在有机化合物和D2O之间进行催化H / D交换。 TpRu（PPh3）（CH3CN）H与水反应生成乙酰氨基配合物TpRu（PPh3）（H2O）（NHC（O）CH3）

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Leung Chung Wing; Zheng Wenxu; Wang Dexian; Ng Siu Man; Yeung Chi Hung; Zhou Zhongyuan; Lin Zhenyang; Lau Chak Po;
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1. Catalytic H/D exchange between organic compounds and D2O with TpRu(PPh3)(CH3CN)H (Tp = hydro(trispyrazolyl)borate). Reaction of TpRu(PPh3)(CH3CN)H with water to form acetamido complex TpRu(PPh3)(H2O)(NHC(O)CH3) [J] . Leung CW, Zheng WX, Wang DX, Organometallics . 2007,第8期

机译：用TpRu（PPh3）（CH3CN）H（Tp =氢（三吡唑基）硼酸酯）在有机化合物和D2O之间进行催化H / D交换。 TpRu（PPh3）（CH3CN）H与水反应形成乙酰氨基配合物TpRu（PPh3）（H2O）（NHC（O）CH3）
2. Octahedral Ru(II) amido complexes TpRu(L)(L ')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L ' = P(OMe)(3) or PMe3 or L = CO and L ' = PPh3; R = H, Ph, or Bu-t): Synthesis, characterization, and reactions with weakly acidic C-H bonds [J] . Conner D., Jayaprakash KN., Wells MB., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第15期

机译：八面体Ru（II）酰胺配合物TpRu（L）（L'）（NHR）（Tp =氢化三（吡唑基）硼酸酯; L = L'= P（OMe）（3）或PMe3或L = CO和L'= PPh3 ; R = H，Ph或Bu-t）：弱酸性CH键的合成，表征和反应
3. Influence of filled d pi-manifold and L/L ' ligands on the structure, basicity, and bond rotations of the octahedral and d(6) amido complexes TpRu(L)(L ')(NHPh) (Tp = hydridotris(pyrazolyl)borate; L= L ' = PMe3 or P(OMe)(3), or L = CO and L ' = PPh3) [J] . Conner D., Jayaprakash KN., Gunnoe TB., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2002,第11期

机译：填充的pi歧管和L / L'配体对八面体和d（6）酰胺配合物TpRu（L）（L'）（NHPh）（Tp =氢化三（吡唑基））的结构，碱性和键旋转的影响硼酸盐; L = L'= PMe3或P（OMe）（3），或L = CO且L'= PPh3）
4. Catalytic H/D exchange between organic compounds and D2O with TpRu(PPh3)(CH3CN)H (Tp = hydro(trispyrazolyl)borate). Reaction of TpRu(PPh3)(CH3CN)H with water to form acetamido complex TpRu(PPh3)(H2O)(NHC(O)CH3) [O] . Leung CW, Zheng W, Wang D, 2007

机译：用TpRu（PPh3）（CH3CN）H（Tp =氢（三吡唑基）硼酸酯）在有机化合物和D2O之间进行催化H / D交换。 TpRu（PPh3）（CH3CN）H与水反应形成乙酰氨基配合物TpRu（PPh3）（H2O）（NHC（O）CH3）

Catalytic H/D exchange between organic compounds and D2O with TpRu(PPh3)(CH3CN)H (Tp = hydro(trispyrazolyl)borate). Reaction of TpRu(PPh3)(CH3CN)H with water to form acetamido complex TpRu(PPh3)(H2O)(NHC(O)CH3)

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