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Microemulsions in oil-water-surfactant mixtures: Systematics of a lattice-gas model

机译:油-水-表面活性剂混合物中的微乳液:晶格气体模型的系统学

摘要

A lattice-gas model is constructed for oil-water-surfactant mixtures. The phase diagram of this model is obtained by using mean-field theory and Monte Carlo simulations aided by low temperature expansions. Microstructures, structure factors, and mean droplet lifetimes are also determined in some phases. Both two and three dimensions are studied, the former in more detail than the latter. It is shown that it is natural to interpret the paramagnetic phase in our model as a microemulsion. Our model is found to exhibit various properties that are in qualitative agreement with experimental observations of oil-water-surfactant mixtures: (1) two- and three-phase coexistence occurs between oil-rich, water-rich, and microemulsion phases along first-order phase boundaries or a triple line in certain regions of the phase diagram of our model; (2) the triple line, which ends in a tricritical point, is short and this leads to low oil- microemulsion and water-microemulsion interfacial tensions; (3) microstructures (including bicontinuous ones in three dimensions) and structure factors are similar to some experimental ones; (4) droplets in our microemulsion phase are long lived like their experimental counterparts; ( 5 ) long-lived, metastable phases, including long-period, lamellar, and glasslike phases, appear at low temperatures. The limitations of our model are discussed. Our study is compared with other studies of models of oil-water-surfactant mixtures.
机译:建立了油-水-表面活性剂混合物的晶格气模型。该模型的相图是通过使用平均场理论和借助低温膨胀的蒙特卡洛模拟获得的。在某些阶段还确定了微结构,结构因素和平均液滴寿命。对二维和三维都进行了研究,前者比后者更详细。结果表明,将我们模型中的顺磁相解释为微乳液是很自然的。我们的模型显示出与油-水-表面活性剂混合物的实验观察定性一致的各种特性:(1)富油,富水和微乳液相沿第一相出现了两相和三相共存。在模型的相图的某些区域中排序相界或三线; (2)终止于三临界点的三线短,导致油-微乳液和水-微乳液的界面张力低; (3)微观结构(包括三维的双连续结构)和结构因子与某些实验相似; (4)微乳液相中的液滴像它们的实验对应物一样寿命长; (5)长期出现的亚稳态相,包括长相,层状和玻璃状相,在低温下出现。讨论了我们模型的局限性。我们的研究与油水表面活性剂混合物模型的其他研究进行了比较。

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