First total synthesis of yanuthones: novel farnesylated epoxycyclohexenoid marine natural products

摘要

The total synthesis of the recently isolated marine natural products of mixed biosynthetic origin, yanuthones A, 13 C and 22-deacylyanuthone A,has been accomplished following a short regio- and stereocontrolled approach involving the key intermediacy of 2-farnesyl-p-benzoquinone.