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Fabrication And Properties Of Transparent, Conductive And Flexible Multi-Walled Carbon Nanotubes (Mwcnts)/Epoxy Composite Film

机译:透明,导电和柔性多壁碳纳米管/环氧树脂复合膜的制备及性能

摘要

Optically transparent, conductive, and mechanically flexible epoxy thin films nanocomposite are produced in the present study. Investigations on the properties of different epoxy/hardener ratios, two different aspect ratios of multiwalled carbon nanotubes (MWCNTs) and MWCNTs loading in epoxy were carried out. The tensile test and dynamic mechanical analysis (DMA) results show that the properties of the epoxy system are governed by different resin/hardener ratios. It was shown that the specimens with an epoxy-to-hardener ratio of 100: 45 (Systems A) exhibit higher tensile strength, Young’s modulus and storage modulus compared to an epoxy-to-hardener ratio of 100: 60 (System B). Two types of MWCNTs with different aspect ratios and loadings were dispersed in epoxy resin through an ultrasonication process and compression molded to form the epoxy thin films nanocomposite. Results showed that nanocomposites containing MWCNTs with a lower aspect ratio (S-MWCNTs) exhibit enhanced electrical conductivity compared to those with a higher aspect ratio (L-MWCNTs). Higher Young’s modulus, tensile strength and thermal stability were observed in S-MWCNTs thin film nanocomposite if compared to those of L-MWCNTs. This behavior was associated with the better S-MWCNTs dispersion in the epoxy resin. A sheet resistance as low as 100 Ω/sq with nearly 60 % optical transparency in 550 nm is achieved with the addition of MWCNTs in epoxy.
机译:在本研究中产生了光学透明,导电和机械柔性的环氧薄膜纳米复合材料。研究了不同比例的环氧/固化剂,两种不同长宽比的多壁碳纳米管(MWCNTs)和负载在环氧树脂中的MWCNTs的性能。拉伸试验和动态力学分析(DMA)结果表明,环氧体系的性能受不同的树脂/固化剂比率控制。结果表明,与环氧与固化剂之比为100:60(系统B)相比,环氧与固化剂之比为100:45(系统A)的样品显示出更高的拉伸强度,杨氏模量和储能模量。通过超声处理将两种具有不同长径比和负载的MWCNTs分散在环氧树脂中,并进行压缩成型,以形成环氧薄膜纳米复合材料。结果表明,与具有较高长径比的纳米复合材料(L-MWCNTs)相比,包含低纵横比的MWCNT(S-MWCNTs)的纳米复合材料表现出增强的电导率。与L-MWCNT相比,S-MWCNTs薄膜纳米复合材料具有更高的杨氏模量,拉伸强度和热稳定性。此行为与S-MWCNT在环氧树脂中的分散性更好有关。通过在环氧树脂中添加MWCNT,可以实现低至100Ω/ sq的薄层电阻以及在550 nm下具有近60%的光学透明性。

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    Saw Lian Na;

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  • 年度 2012
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