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Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain

机译：带有手性烷基链的聚异亚丁基菲氨酸的合成及性能

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We synthesized poly(isothianaphthene methine)s with chiral alkyl chains in the substituent. Resultant polymers are soluble in THF and CHCl3. Structure of the polymers was characterized with FT-IR, FT-Raman, and UV-Vis-NIR optical absorption spectroscopy. They showed low-bandgap both in solution and in a form of film. Optical activity of the polymers was confirmed with optical rotatory dispersion. Doping effects on the polymer were also examined with UV-Vis-NIR spectroscopy and ESR measurement.

机译：我们合成了在取代基中具有手性烷基链的聚（异亚锡亚甲基）。所得聚合物可溶于THF和CHCl 3。用FT-IR，FT-拉曼和UV-Vis-NIR光吸收光谱法表征聚合物的结构。他们在溶液和薄膜形式中均显示出低带隙。用旋光色散证实了聚合物的旋光性。还通过UV-Vis-NIR光谱和ESR测量检查了对聚合物的掺杂效果。

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作者
Innami Yu; Kawashima Hirotsugu; Kiebooms Rafaël H. L.; Aizawa Hideaki; Matsuishi Kiyoto; Goto Hiromasa;
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年度 2012
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正文语种 en
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专利

1. Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain [J] . Hideaki Aizawa, Hiromasa Goto, Hirotsugu Kawashima, Materials . 2010,第2期

机译：带有手性烷基链的聚异硫醚甲硫氨酸的合成与性能
2. Synthesis and characterisation of poly(isothianaphthene methine). [J] . Kiebooms R., Wudl F. Synthetic Metals . 1999,第1a3期

机译：聚异亚锡亚甲基的合成与表征。
3. Effects of alkyl or alkyloxy side chains in poly[4,6-bis(3 '-dodecylthien2 '-yl)thieno-[3,4-c][1,2,5]thiadiazole-5 ',5 '-diyl-alt-2,5-di(alkyl or alkyloxy)-1,4-phenylene]: Synthesis, photophysics, and spectroelectrochemical and photovoltaic properties [J] . Cimrova Vera, Pokorna Veronika, Vyprachticky Drahomir Polymer: The International Journal for the Science and Technology of Polymers . 2017,第期

机译：烷基或烷氧基侧链在聚[4,6-双（3'-二十二烷噻吩2' - yl）噻吩-[3,4-c] [1,2,5]噻二唑-5'，5' - 二谷 - ALT-2,5-二（烷基或烷基氧基）-1,4-亚苯基]：合成，光药和光谱电化学和光伏性能
4. Main-Chain Chiral Poly(2-oxazoline)s: Influence of Alkyl Side-Chain on Secondary Structure Formation in the Solid State [C] . Meta M. Bloksma, Marco M. R. M. Hendrix, Silke Rathgeber International Symposium on Ionicolymerization . 2015

机译：主要链手性聚（2-恶唑啉）S：烷基侧链对固态次级结构形成的影响
5. Synthesis, characterization, fiber spinning, and mechanical properties of poly(benzobisthiazole)s with substituted biphenyl moieties in the main chain. [D] . Hu, Xiaodong. 1997

机译：主链中带有取代联苯部分的聚（苯并双噻唑）s的合成，表征，纤维纺丝和力学性能。
6. Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain [O] . Yu Innami, Hirotsugu Kawashima, Rafaël H. L. Kiebooms, 2012

机译：带有手性烷基链的聚异亚丁基菲氨酸的合成及性能
7. Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain [O] . Hiromasa Goto, Hideaki Aizawa, Kiyoto Matsuishi, 2012

机译：手性烷基链聚（异噻吩甲醚）的合成与性质
8. Studies of Chain Conformational Kinetics in Poly(Di n-Alkyl Silanes) by Spectroscopic Methods. 1. Poly(Di n-Hexylsilane), Poly(Di n-Heptylsilane) and Poly(Di n-Octysilane) [R] . Rabolt, J. F., Hofer, D., Miller, R. D., 1986

机译：光谱法研究聚（二正烷基硅烷）链构象动力学。 1.聚（二正己基硅烷），聚（二正庚基硅烷）和聚（二正辛基硅烷）

Synthesis and Properties of Poly(Isothianaphthene Methine)s with Chiral Alkyl Chain

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