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High temperature Brillouin scattering study on elastic properties of lithium cesium borate glasses, crystals and melts

机译:高温布里渊散射研究硼酸铯铯玻璃,晶体和熔体的弹性

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摘要

The mixed alkali effect on elastic properties of lithium cesium borate glasses 0.25[xLi2O − (1 − x) Cs2O] − 0.75B2O3 was studied by Brillouin scattering. The observed mixed alkali effect on the negative deviation from linearity in the composition dependence of longitudinal modulus was discussed on the basis of the decrease of four-fold coordinated boron atoms and the increase of nonbridging oxygens. The temperature dependence of elastic properties was studied in the large temperature range from room temperature to 1500 K to clarify the differences between glasses, crystals and melts. The influence of annealing was clearly observed in LA sound velocity. Fragility was discussed using the temperature dependence of velocity.
机译:通过布里渊散射研究了混合碱对硼酸铯铯玻璃0.25 [xLi2O-(1-x)Cs2O]-0.75B2O3弹性性能的影响。基于四倍配位硼原子的减少和非桥联氧的增加,讨论了所观察到的混合碱对纵向模量组成相关性的线性负偏差的影响。在室温至1500 K的较大温度范围内研究了弹性性能的温度依赖性,以阐明玻璃,晶体和熔体之间的差异。在洛杉矶声速中清楚地观察到了退火的影响。使用速度的温度依赖性讨论了脆性。

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