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Hydrodynamic and mass transfer efficiency of ceramic foam packing applied to distillation

机译:陶瓷泡沫填料用于蒸馏的流体力学和传质效率

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摘要

In addition to a high void volume and specific area, solid foams possess other properties (low density, good thermal, mechanical, electrical, and acoustical behaviour) that make them attractive for applications such as heat exchangers and reformers. Applications using foams as catalysts or structured catalyst supports have demonstrated higher performance than classical catalysts. Several studies have explored the hydrodynamic behaviour of foams in monophasic and counter current systems and have reported very low pressure drops. This paper describes the application of ceramic foam to distillation. The β-SiC foam contains 5 pores per inch (PPI) with a 91% void volume and a surface area of 640 m2/m3. Performance parameters including pressure drop for the dry and wet packing, flooding behaviour, and dynamic liquid hold-up were measured in a column of 150 mm internal diameter. The mass transfer efficiency in terms of the height equivalent to theoretical plate (HETP) was determined by total reflux experiments using a mixture of n-heptane and cyclohexane at atmospheric pressure. The experimental results were used to develop a set of correlations describing pressure drop and liquid hold-up in terms of a dimensionless number. The hydrodynamic performance and mass transfer efficiency were compared with classical packing materials used in distillation.
机译:除了高空隙体积和比表面积外,固体泡沫还具有其他特性(低密度,良好的热,机械,电和声学性能),使其对热交换器和重整器等应用具有吸引力。使用泡沫作为催化剂或结构化催化剂载体的应用已证明比传统催化剂具有更高的性能。多项研究探索了泡沫在单相和逆流系统中的流体力学行为,并报告了非常低的压降。本文介绍了陶瓷泡沫在蒸馏中的应用。 β-SiC泡沫包含每英寸5个孔(PPI),空隙体积为91%,表面积为640 m2 / m3。在150 mm内径的色谱柱中测量了性能参数,包括干,湿填料的压降,溢流性能和动态持液量。通过在正压下使用正庚烷和环己烷的混合物进行全回流实验,确定了相当于理论塔板高度(HETP)的传质效率。实验结果用于建立一组相关性,以无因次数描述压降和液体滞留率。将流体力学性能和传质效率与蒸馏中使用的传统填料进行了比较。

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