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Shaping of nanostructured materials or coatings through Spark Plasma Sintering

机译:通过火花等离子烧结成型纳米结构材料或涂层

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摘要

In the field of advanced ceramics, Spark Plasma Sintering (SPS) is known to be very efficient for superfast and full densification of ceramic nanopowders. This property is attributed to the simultaneous application of high density dc pulsed current and load, even though the sintering mechanisms involved remain unclear. In the first part of the paper, the mechanisms involved during SPS of two insulating oxide nanopowders (Al2O3 and Y2O3) are discussed while in the second part illustrations of the potential of SPS will be given for (i) Consolidation of mesoporous or unstable nanomaterials like SBA-15 or biomimetic apatite, respectively; (ii) Densification of core (BT or BST)/shell (SiO2 or Al2O3) nanoparticles with limited or controlled reaction at the interface. (iii) In-situ preparation of surface-tailored FeœFeAl2O4œAl2O3 nanocomposites, and finally (iv) One-step preparation of multilayer materials like a complete thermal barrier system on single crystal Ni-based superalloy.
机译:在高级陶瓷领域,火花等离子烧结(SPS)对于超快和完全致密化陶瓷纳米粉非常有效。该特性归因于高密度直流脉冲电流和负载的同时施加,即使所涉及的烧结机制仍不清楚。在本文的第一部分中,讨论了两种绝缘氧化物纳米粉末(Al2O3和Y2O3)的SPS涉及的机理,而在第二部分中,将说明SPS的潜力,用于(i)固结介孔或不稳定的纳米材料,例如SBA-15或仿生磷灰石; (ii)核(BT或BST)/壳(SiO2或Al2O3)纳米颗粒的致密化,界面处的反应受到限制或控制。 (iii)原位制备表面定制的Fe–FeAl2O4–Al2O3纳米复合材料,最后(iv)一步法制备多层材料,例如在单晶Ni基高温合金上形成完整的热障系统。

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