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The Preparation of Non-aqueous Supercapacitors with Lithium Transition-Metal Oxide/Activated Carbon Composite Positive Electrodes

机译:锂过渡金属氧化物/活性炭复合正电极制备非水超级电容器

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摘要

In order to increase the specific capacitance and energy density of supercapacitors, non-aqueous supercapacitors were prepared using lithium transition-metal oxides and activated carbons as active materials The electrochemical properties were analyzed in terms of the content of lithium transition-metal oxides The results of cyclic voltammetry and AC-impedance analyses showed that the pseudocapacitance may stem from the synergistic contributions of capacitive and faradic effects, the former is due to the electric double layer which is prepared in the interface of activated carbon and organic electrolyte, and the latter is due to the intercalation of lithium (Li+)ions The specific capacitance and energy density of a supercapacitor improved as the lithium transition-metal oxides content increased, showing 60% increase compared to those of supercapacitor using a pure activated carbon positive electrod
机译:为了增加超级电容器的比电容和能量密度,使用锂过渡金属氧化物和活性炭作为活性材料制备了非水超级电容器。根据锂过渡金属氧化物的含量分析了电化学性能。循环伏安法和交流阻抗分析表明,伪电容可能源于电容和法拉第效应的协同作用,前者是由于在活性炭和有机电解质的界面中制备了双电层,而后者是由于锂(Li +)离子的嵌入超级电容器的比电容和能量密度随锂过渡金属氧化物含量的增加而提高,与使用纯活性炭正极的超级电容器相比,增加了60%

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