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One-step hydrothermal synthesis of graphene decorated V2O5 nanobelts for enhanced electrochemical energy storage

机译:一步法水热合成石墨烯修饰的V2O5纳米带以增强电化学储能

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摘要

Graphene-decorated V2O5 nanobelts (GVNBs) were synthesized via a low-temperature hydrothermal method in a single step. V2O5 nanobelts (VNBs) were formed in the presence of graphene oxide, a mild oxidant, which also enhanced the conductivity of GVNBs. From the electron energy loss spectroscopy analysis, the reduced graphene oxide (rGO) are inserted into the layered crystal structure of V2O5 nanobelts, which further confirmed the enhanced conductivity of the nanobelts. The electrochemical energy-storage capacity of GVNBs was investigated for supercapacitor applications. The specific capacitance of GVNBs was evaluated using cyclic voltammetry (CV) and charge/discharge (CD) studies. The GVNBs having V2O5-rich composite, namely, V(3)G(1) (VO/GO = 3:1), showed superior specific capacitance in comparison to the other composites (V(1)G(1) and V(1)G(3)) and the pure materials. Moreover, the V(3)G(1) composite showed excellent cyclic stability and the capacitance retention of about 82% was observed even after 5000 cycles.
机译:通过低温水热法一步一步合成了石墨烯修饰的V2O5纳米带。 V2O5纳米带(VNB)是在氧化石墨烯(一种弱氧化剂)的存在下形成的,这也增强了GVNB的电导率。根据电子能量损失谱分析,将还原的氧化石墨烯(rGO)插入V2O5纳米带的层状晶体结构中,这进一步证实了纳米带的导电性增强。研究了超级电容器应用中GVNB的电化学储能能力。使用循环伏安法(CV)和充电/放电(CD)研究评估了GVNB的比电容。具有富含V2O5的复合材料即V(3)G(1)(VO / GO = 3:1)的GVNB比其他复合材料(V(1)G(1)和V( 1)G(3))和纯材料。此外,V(3)G(1)复合材料表现出出色的循环稳定性,即使在5000次循环后仍观察到约82%的电容保持率。

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