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PROCESS FOR THE DIRECT PRODUCTION OF TUNGSTEN CARBIDE POWDERS OF VARIOUS GRAIN SIZES STARTING FROM SCHEELITE

机译:从白闪石直接生产各种粒度的碳化钨粉的方法

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摘要

The invention relates to a process which allows to obtain powders of tungsten carbide directly from tungsten ores belonging to the class of scheelite by carbothermic reduction carried out in non-drastic conditions with regard to the times and/or temperatures, and in which the obtained powders may have different particle size as said treatment conditions are varying.udThe process starts from powders of scheelite (CaWO4) and carbon in proportions such as to have a maximum excess of carbon, compared to the expected conversion reaction, of about 5-6% by weight, mixed with the 0,4-6% by weight of powder of one or more transition metals of the former group VIIIB (now groups 8, 9 and 10), in particular Co, Ni or Fe, as the promoter of the conversion in carbide and/or as activator of the WC grain growth, and comprises a powder grinding step, a heat treatment step of the mixture of powders obtained by milling at temperatures between 900 and 1500°C in an inert atmosphere or under vacuum, and a step of purification of the resulting powder by leaching of residual oxides.
机译:本发明涉及一种方法,该方法允许通过在非剧烈条件下关于时间和/或温度进行的碳热还原直接从属于白钨矿类别的钨矿石中获得碳化钨粉末,并且其中获得的粉末 ud此过程始于白钨矿(CaWO4)和碳的粉末,其比例使得与预期的转化反应相比,碳的最大过量为约5-6%与0.4重量%的粉末混合,将0.4VIII重量%的一种或多种前者VIIIB族的过渡金属(现在是第8、9和10族),特别是Co,Ni或Fe作为助催化剂。碳化物的转化和/或作为WC晶粒长大的活化剂,包括粉末研磨步骤,在惰性气氛中或在真空下于900至1500°C的温度下研磨得到的粉末混合物的热处理步骤,以及一个 通过沥滤残余氧化物纯化所得粉末的步骤。

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