Development of matte finishes in electrostatic (EFB) and conventional hot dipping (CHDFB) fluidized bed coating process

摘要

This study focuses on the correlation between the thermo-rheological properties of a thermosetting powder coating system with its surface structure build-up. Epoxy powder coating systems, which displayed surface matting and surface wrinkling, were examined. Firstly, the evolution of the complex viscosity was correlated with the cure kinetic. Secondly, the structure build-up on the surface of the coatings was investigated with a combined SEM-CLA profilometry analysis at different stages of curing process for both EFB and CHDFB coating processes. Different finishes were found to characterize the films applied by using EFB and CHDFB coating processes as a result of the different way the film is heated by. Finally, a strict relationship of film morphology to the degree of conversion and to the evolution of the complex viscosity was found out for both EFB and CHDFB coating processes. The surface structure is built up after gelation point and continues to evolve after gelation with a full development of the film fine structure. Differences were observed in the surface structure build-up when different curing temperature was used, thereby indicating an influence of minimum viscosity on achievable finishing. These experimental results lead to further advances in a better understanding of the formation of surface topography and morphology of polymeric films. They also provide important indications for the settings of curing parameters in both EFB and CHDFB coating processes as well as for the development of new powder coating formulations. © 2007 Elsevier B.V. All rights reserved.