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Assessment of chromate and chromate-free conversion coatings for the corrosion protection of aerospace aluminum alloy

机译:评估用于航空航天铝合金腐蚀的铬酸盐和无铬转化膜

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摘要

Aerospace aluminum alloys, especially the most commonly used AA 2024 T3 alloy is often susceptible to corrosion in chloride containing environment. These alloys are phase separated, highly complex metal-in-metal composites and tend to have weakness towards local galvanic corrosion because of this microstructure. At present the coating system used for aerospace aluminum alloys involves a multi-layer system such as a pretreatment layer at the primer/Al-alloy substrate interface, primer and topcoat. Chromate conversion coatings (CCCs) are usually applied as pretreatment layer to aluminum and its alloys. Despite its efficiency and versatility, the use and emission of hexavalent chromium (Cr6+) has been under increasingly strict regulation because of its high toxicity and carcinogenic effect. For the past two decades concentrated efforts were made to develop an ecofriendly conversion coating system as an alternative to CCC and also chromate free additives in primer layer.
机译:航空航天铝合金,尤其是最常用的AA 2024 T3合金通常容易在含氯的环境中腐蚀。这些合金是相分离的高度复杂的金属对金属复合材料,由于这种微观结构,它们倾向于对局部电化腐蚀无能为力。目前,用于航空航天铝合金的涂层系统涉及多层系统,例如在底漆/铝合金基材界面,底漆和面漆上的预处理层。铬酸盐转化膜(CCC)通常作为预处理层应用于铝及其合金。尽管六价铬(Cr6 +)具有高效率和多功能性,但由于其高毒性和致癌作用,其使用和排放受到越来越严格的管制。在过去的二十年中,人们一直在致力于开发一种环保型转化涂料系统,以替代CCC以及底漆层中不含铬的添加剂。

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    Balaraju JN;

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  • 年度 2013
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  • 原文格式 PDF
  • 正文语种 {"code":"en","name":"English","id":9}
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