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Experimental and modelling studies of the shape memory properties of amorphous polymer network composites

机译:非晶态聚合物网络复合材料形状记忆特性的实验和建模研究

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摘要

Shape memory polymer composites (SMPCs) have become an important leverage to improve the development of shape memory polymers (SMPs) applications. An amorphous SMP matrix has been filled with different types of reinforcements in this study. An experimental set of results is presented and then compared to 3D finite element simulations. Thermomechanical shape memory cycles were performed in uniaxial tension. The fillers effect was studied in stress-free and constrained-strain recoveries. Experimental observations indicate complete shape recovery and put in evidence the increased sensitivity of constrained length stress recoveries to the heating ramp on the tested composites. The simulations reproduced a simplified periodic reinforced composite and use a model for the matrix material that has been previously tested on regular SMPs. The latter combines viscoelasticity at finite strain and time-temperature superposition. The simulations permit to represent the recovery properties of a reinforced SMP easily.
机译:形状记忆聚合物复合材料(SMPC)已成为改善形状记忆聚合物(SMP)应用程序开发的重要手段。在这项研究中,无定形的SMP基质填充了不同类型的增强材料。提出了一组实验结果,然后将其与3D有限元模拟进行了比较。热机械形状记忆循环在单轴张力下进行。研究了填料在无应力和约束应变恢复下的效果。实验观察表明,完全恢复了形状,并证明了受约束的长度应力恢复对测试复合材料加热坡道的敏感性提高。模拟复制了简化的周期性增强复合材料,并使用了先前已在常规SMP上测试过的基质材料模型。后者将有限应变下的粘弹性与时温叠加相结合。这些模拟可以轻松表示增强型SMP的恢复特性。

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