首页> 外文OA文献 >Élaboration et étude des propriétés électriques d'un matériau composite nanotubes de carbone alignés - époxy
【2h】

Élaboration et étude des propriétés électriques d'un matériau composite nanotubes de carbone alignés - époxy

机译:复合材料排列的碳纳米管-环氧树脂电学性质的研究进展。

摘要

This study presents first the fabrication of a composite material based on Multi-Walled Carbon Nanotubes (MWNT/CNT) synthesised by an aerosol-assisted Catalytic Chemical Vapour Deposition (CCVD) process into continuous and verticaly aligned carpets, and on an epoxy polymer matrix. Then the characterisation of the material's structure and surface is described. And then, its electrical transport properties are studied. The electrical conduction at room temperature is measured. First, locally by a Current-Sensing AFM (CS-AFM) so that the CNTs are characterized at an individual scale. Then, at the macroscopic scale, so that the material's properties are characterized when its size is easy at use. This study shows that the resistivity is low and anisotropic. Significant fluctuations (approximatively by a factor 10) in the macroscopic resistance exist from one measurement to an other. The nature of these fluctuations is discussed. The electrical conduction at low temperature (from 4 to 50◦K) displays at a macroscopic scale the same mesoscopic electric transport properties than individual CNTs. In particular, a conductance scaling law in function of the temperature and the voltage ("Zero Bias Anomaly") has been observed, as well as a weaklocalization (WL) law. Moreover, the conductance distribution measured by CS-AFM allows to demonstrate this persistence's origin with a simple and realistic model.
机译:这项研究首先介绍了基于多层碳纳米管(MWNT / CNT)的复合材料的制造,该复合材料是通过气溶胶辅助催化化学气相沉积(CCVD)工艺合成为连续和垂直排列的地毯,以及环氧聚合物基体。然后描述了材料的结构和表面的特征。然后,研究了其电传输性质。测量室温下的电导率。首先,通过电流感应AFM(CS-AFM)在本地进行处理,以便对CNT进行个性化表征。然后,在宏观尺度上,使材料的特性在易于使用时得到表征。这项研究表明,电阻率低且各向异性。从一种测量到另一种测量,存在宏观电阻的显着波动(约为10倍)。讨论了这些波动的性质。低温下(从4到50°K)的导电在宏观上显示出与各个CNT相同的介观电传输性质。特别地,已经观察到随温度和电压变化的电导比例定律(“零偏置异常”),以及弱局部化(WL)定律。此外,通过CS-AFM测量的电导分布可以通过简单而现实的模型证明这种持久性的起源。

著录项

  • 作者

    Roussel Florent;

  • 作者单位
  • 年度 2012
  • 总页数
  • 原文格式 PDF
  • 正文语种 fr
  • 中图分类

相似文献

  • 外文文献
  • 中文文献
  • 专利

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号