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Crystallographic evidence for reversible symmetry breaking in a spin-crossover d7 cobalt(II) coordination polymer

机译:自旋交联的d7钴(II)配位聚合物中可逆对称性断裂的晶体学证据

摘要

All in a spin: A cobalt(II) coordination polymer has a highly cooperative spin-crossover (SCO) behavior with a small hysteresis loop (see picture; HS=high spin, LS=low spin). The correlation of the magnetic properties with the crystal structures was determined at different temperatures. This study reveals an unprecedented reversible symmetry breaking in a d7 SCO coordination polymer.
机译:处于自旋状态:钴(II)配位聚合物具有高度协作的自旋交越(SCO)行为和小的磁滞回线(参见图片; HS =高自旋,LS =低自旋)。在不同温度下测定了磁性与晶体结构的相关性。这项研究揭示了d7 SCO配位聚合物中前所未有的可逆对称性破坏。

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