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Model compounds for the active sites of oxo-transfer molybdoenzymes. Synthesis, structural characterization, and electrochemical properties of NH42MoO2{O2CC(S)Ph2}2

机译:羰基转移钼酶活性位点的模型化合物。 NH4 2 MoO2 {O2CC(S)Ph2} 2的合成,结构表征和电化学性质

摘要

[NH4]2[MoO2{O2CC(S)Ph2}2]middot;2H2O has been prepared and its crystal structure solved, providing the first example of a co-ordinatively saturated molybdenum complex which reacts readily and reversibly with organophosphines at room temperature in water or methanol; its variable-temperature 13C{1H} NMR spectra and electrochemical properties are presented.
机译:制备了[NH4] 2 [MoO2 {O2CC(S)Ph2} 2] 2H2O并解决了其晶体结构,提供了一个配位饱和的钼配合物的第一个实例,该配合物在室温下易于与有机膦发生可逆反应。水或甲醇;给出了其可变温度13C {1H} NMR光谱和电化学性质。

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