CO2 controlled flocculation of microalgae using pH responsive cellulose nanocrystals

摘要

Cellulose nanocrystals were grafted with imidazole functionalities up to DS 0.06 using a one-pot functionalization strategy. The resulting nanocrystals were shown to have a pH responsive surface charge which was found to be positive below pH 6 and negative above pH 7. These imidazolyl cellulose nanocrystals were tested for flocculation of Chlorella vulgaris using CO2 to induce flocculation. Up to 90 % flocculation efficiency was achieved with 200 mg L−1 dose. Furthermore, the modified cellulose nanocrystals showed good compatibility with the microalgae during cultivation, giving potential for the production of reversible flocculation systems.