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Organo-lanthanide complexes as luminescent dopants in polymer waveguides fabricated by hot embossing

机译:有机镧系配合物在通过热压花加工制成的聚合物波导中作为发光掺杂剂

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摘要

Lanthanide complexes, Eu(dbM)(3)(Phen) and Er(dbM)(3)(Phen), are employed as luminescent dopants within polymer channel waveguide devices fabricated by hot embossing. Spectroscopic properties of the complexes as dopants in the waveguide core polymer are investigated in detail. Judd-Ofelt parameters are calculated for the europium chelate and radiative properties are determined viz. potential for optical amplification. Channel waveguides fabricated by single level embossing are shown to be capable of guiding visible and infrared light emitted following optical excitation of the dopants. Multi-level polymer micro-optical benches incorporating doped channel waveguides and passive locational features for self-alignment and integration of optical fibres are fabricated in a multi-level single-step embossing process and are shown to successfully out-couple the waveguided dopant emission.
机译:镧系元素配合物Eu(dbM)(3)(Phen)和Er(dbM)(3)(Phen)被用作通过热压花制造的聚合物通道波导器件中的发光掺杂剂。详细研究了复合物在波导芯聚合物中作为掺杂剂的光谱性质。计算for螯合物的Judd-Ofelt参数,并确定辐射性能。光放大的潜力。示出了通过单级浮雕制造的通道波导能够引导在掺杂剂的光激发之后发射的可见光和红外光。在多层单步压花工艺中制造了具有掺杂通道波导和无源位置特征的多级聚合物微光学平台,这些特性用于光纤的自动对准和集成,并且显示出能够成功地耦合出波导的掺杂物发射。

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