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Perspectives for the recovery of rare earths from end-of-life fluorescent lamps

机译:寿命终止日光灯回收稀土的前景

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摘要

This vision paper discusses the advantages and disadvantages of the three main options for the recycling of rare-earth elements from end-of-life fluorescent lamps: (1) direct re-use of the lamp phosphor mixture; (2) separation of the lamp phosphor mixture into the different phosphor components; (3) recovery of the rare-earth content. An overview is given of commercial activities inEurope in the domain of recycling of materials from end-of-life fluorescent lamps and the recovery of rare earths from these lamps. The collection of end-of-life fluorescent lamps is currently driven by a legal framework that prohibited the release of mercury to the environment. The contaminations of the lamp phosphor powders by mercury and by small glass particles of crushed fluorescent lamps are limiting factors in the recycling process. Research should be directed to an advanced clean-up of the reclaimed lamp phosphor fraction, and in particular to the removal of mercury and glass fragments. The recovery of rare earths from the lamp phosphors could be facilitated by taking advantage of the differences in resistance of the different lamp phosphors by chemical attack by inorganic acids and bases.
机译:本远景文件讨论了报废荧光灯中稀土元素再循环的三个主要选择的优缺点:(1)直接重复使用灯的荧光粉混合物; (2)将灯的荧光粉混合物分离成不同的荧光粉成分; (3)回收稀土含量。概述了欧洲在报废荧光灯的材料回收和从这些灯中回收稀土方面的商业活动。当前,报废荧光灯的收集是由禁止向环境中释放汞的法律框架推动的。汞和破碎的荧光灯的小玻璃颗粒对灯荧光粉的污染是回收过程中的限制因素。研究应针对回收的灯的磷光体部分的高级清洁,尤其是汞和玻璃碎片的去除。通过利用无机酸和碱的化学侵蚀,利用不同灯荧光体的电阻差异,可以促进从灯荧光体中回收稀土。

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