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The durability of carbon fiber/epoxy composites under hydrothermal ageing

机译:碳纤维/环氧树脂复合材料在水热老化下的耐久性

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摘要

Studies on fibre reinforced composites are now receiving greater attention. Industrial applications have been successful in areas like aerospace, automobile, marine, construction and sporting goods. The first generation of epoxy resins for use in carbon fibre composites are able to achieve optimized high stiffness modules and high heat resistance by a high crosslink density, reached through thermal curing. However, these formulations can be very toxic and brittle with low crack resistance, which was a major disadvantage for structural applications. In the last years the use of ionizing radiation as alternative to thermal curing has been proposed as an environmentally friendly process. Furthermore, in order to enhance toughness mechanical requirements for their applications, the formulation generally consists of blends of epoxy resins and engineering thermoplastics. In terms of durability (service life and reliability), in these materials it depends on different environmental conditions (temperature, moisture, etc.), and it is very important to know how their properties are modified after the exposure to different temperature and moisture absorption cycles. In this work carbon fibre composites produced by ionizing radiation induced curing of the epoxy based matrices have been subjected to thermal and moisture absorption ageing and the influence of these treatments on the thermal and mechanical properties has been investigated through dynamic mechanical thermal analysis and mechanical fracture toughness tests.
机译:纤维增强复合材料的研究现在受到越来越多的关注。工业应用已在航空航天,汽车,船舶,建筑和体育用品等领域获得成功。用于碳纤维复合材料的第一代环氧树脂能够通过热固化达到高交联密度,从而实现优化的高刚度模块和高耐热性。然而,这些制剂可能具有很高的毒性和脆性,并且抗裂性低,这是结构应用的主要缺点。近年来,已经提出使用电离辐射代替热固化是一种环境友好的方法。此外,为了提高其应用的机械强度要求,该配方通常由环氧树脂和工程热塑性塑料的混合物组成。在耐用性(使用寿命和可靠性)方面,在这些材料中,它取决于不同的环境条件(温度,湿度等),了解暴露于不同温度和水分吸收后其性能如何变化非常重要。周期。在这项工作中,通过电离辐射诱导的环氧树脂基基体的固化生产的碳纤维复合材料经历了热和水分吸收老化,并通过动态机械热分析和机械断裂韧性研究了这些处理对热和机械性能的影响。测试。

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