首页> 外文OA文献 >2-Methyl-3-(4-methyl-phen-yl)sulfon-yl-oxy-2-{(4-methyl-phen-yl)sulfon-yloxymeth-yl}propyl 4-methyl-benzene-sulfonate
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2-Methyl-3-(4-methyl-phen-yl)sulfon-yl-oxy-2-{(4-methyl-phen-yl)sulfon-yloxymeth-yl}propyl 4-methyl-benzene-sulfonate

机译:2-甲基-3-(4-甲基-苯基)磺酰基氧基 -2-{((4-甲基-苯基)磺酰基氧基甲基}丙基4-甲基苯-磺酸盐

摘要

The title mol-ecule, C(26)H(30)O(9)S(3), adopts an extended conformation whereby two approximately parallel benzene rings [dihedral angle = 8.32 (10)°] are orientated in opposite directions along the pseudo-threefold axis through the central quaternary C atom, while a third ring occupies a position mid-way and face-on to these rings [dihedral angles = 82.28 (10) and 78.81 (7)°]. The crystal packing is dominated by C-H⋯O contacts and π-π inter-actions [ring centroid distance = 3.6902 (12) Å].
机译:标题分子C(26)H(30)O(9)S(3)具有扩展的构象,其中两个近似平行的苯环[二面角= 8.32(10)°]沿相反的方向取向伪三倍轴穿过中央四级C原子,而第三个环占据这些环的中间位置并面朝上[二面角= 82.28(10)和78.81(7)°]。晶体堆积主要由C-H⋯O接触和π-π相互作用[环质心距离= 3.6902(12)Å]决定。

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