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Improvement in the Mechanical Properties of B-Staged Carbon Nanotube/Epoxy Based Thin Film Systems

机译:B级碳纳米管/环氧树脂基薄膜系统机械性能的改进

摘要

Polymeric systems have been the subject of tremendous interest to the aerospaceindustry due to their high strength per weight ratio but have not seen the use projecteddue to their poor compression after impact strength, fracture toughness, and electricalconductivity. This work has focused on the integration of single walled carbonnanotubes (SWCNTs) into polymeric systems to serve as interleaves to improve themechanical properties of carbon fiber panels. Pristine, oxidized, and functionalizedcarbon nanotubes were produced and cast into B-staged (50% cured) thin film epoxyresin systems. Mechanical characterizations were carried out on bulk samples andshowed that the introduction of well dispersed SWCNTs functionalized withsulfanilamide improved the Young?s modulus of the neat epoxy by 16%, the tensilestrength by 47%, the elongation at break by 157%, and the fracture toughness, asdetermined by KIC, by 10%. Nylon was introduced into the system as a tougheningagent at 10 wt% and showed an 8% increase in the Young?s modulus, a 29% increase inivtensile strength, a 183% increase in elongation at break, and a 44% increase in fracturetoughness. These composite films were successfully transferred into a carbon fiberinterleave using Vacuum Assisted Resin Transfer Molding (VARTM).
机译:聚合物体系由于其高的单位重量比而已成为航空航天工业的极大兴趣,但由于其在冲击强度,断裂韧性和导电性之后的压缩性差,因此尚未见到其用途。这项工作的重点是将单壁碳纳米管(SWCNT)集成到聚合物系统中,以用作提高碳纤维面板力学性能的交错体。生产了原始的,氧化的和功能化的碳纳米管,并浇铸到B级(固化度为50%)的薄膜环氧树脂体系中。对大量样品进行了机械表征,结果表明,引入分散良好的磺胺官能化的SWCNT可使纯环氧的杨氏模量提高16%,拉伸强度提高47%,断裂伸长率提高157%,断裂韧性由KIC确定的10%。尼龙以10 wt%的增韧剂形式引入系统,并表现出杨氏模量增加8%,抗张强度增加29%,断裂伸长率增加183%以及断裂韧性增加44%。使用真空辅助树脂传递模塑(VARTM)将这些复合膜成功地传递到碳纤维衬里中。

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    White Kevin;

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  • 年度 2011
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