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Measuring optical absorption coefficient of pure water in UV using the integrating cavity absorption meter.

机译:使用积分腔吸收计测量纯净水在紫外线下的光学吸收系数。

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摘要

The integrating cavity absorption meter (ICAM) has been used successfully to measurethe low absorption coefficient of pure water. The ICAM produces an effective total pathlength of several meters or even longer, although the physical size of the instrument isonly several centimeters. The long effective total path length ensures a high sensitivitythat enables the ICAM to measure liquid mediums with low absorption. Compared to theconventional transmission type of instruments that were used to measure the samemedium with the same path length, the ICAM eliminates the effect of scattering byintroducing isotropic illumination in the medium, and consequently measures the trueabsorption coefficient of the medium in stead of the attenuation coefficient. The originalICAM was constructed with Spectralon and used in the wavelength range from 380 nmto 700 nm. Later studies showed that Spectralon is not suitable for measurements in theUV region because of its relatively lower reflectivity in this region and, even worse, thecontinuously decaying reflectivity under the exposure to UV radiation. Thus, we havedeveloped a new way to construct the ICAM utilizing the material fumed silica. The resulting ICAM has a high sensitivity even in the UV region and doesn't have thedeterioration problem. The measurement results from the new ICAM are in goodagreement with the existing results. The absorption coefficients of pure water atwavelengths between 250 nm and 400 nm are presented here.
机译:积分腔吸收仪(ICAM)已成功用于测量纯水的低吸收系数。尽管仪器的物理尺寸只有几厘米,但ICAM产生的有效总光程却只有几米甚至更长。较长的有效总路径长度可确保较高的灵敏度,从而使ICAM能够测量吸收率低的液体介质。与用于测量相同路径长度的相同介质的常规传输类型的仪器相比,ICAM通过在介质中引入各向同性照明来消除散射的影响,从而测量介质的真实吸收系数而不是衰减系数。原始的ICAM由Spectralon构建,并在380 nm至700 nm的波长范围内使用。后来的研究表明,Spectralon不适合在UV区域中进行测量,因为它在该区域的反射率相对较低,更糟糕的是,在暴露于UV辐射下,反射率会不断衰减。因此,我们开发了一种利用气相法二氧化硅构造ICAM的新方法。所得的ICAM即使在UV区域也具有高灵敏度,并且不存在劣化问题。新ICAM的测量结果与现有结果非常吻合。此处显示了波长在250 nm至400 nm之间的纯水的吸收系数。

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    Wang Ling;

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  • 年度 2008
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