Effect of the aggressive environment on the damage of a glass polyester composite developed by hand layup process

摘要

This work treats the behavior of a glass fibre/unsaturated polyester (UP) composite with structural deffects subjected to the attack of two corrosive solutions: H2SO4 and NaOH. The gravimetric analysis, the uptake mass of the resin, and the interfaces in the composite are established according to the proportion of the matrix/composite. The obtained results showed that, in the acidic solution, the glass fibre and the fibre/matrix interface absorption share is more significant than the alkaline solution. While the Fourier transform infrared analysis (FT-IR) of the UP resin revealed the presence of chemical degradation phenomenon (hydrolysis), the fibre corrosion was characterized by the atomic absorption analysis (AAS). The fibres/matrix interfaces degradation was confrmed by microscopic observations (SEM). The difusion kinetics of the both acid and alkaline solutions and chemical and mechanical degradation are afected by the presence of the pores in elaborated material