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The effect of crystallization conditions on tantalum distribution in molybdenum and tungsten during electron beam zone melting

机译:电子束区熔化过程中结晶条件对钼和钨中钽分布的影响

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摘要

The distribution of tantalum in molybdenum and tungsten single crystals during electron beam fl oating zone meltingunder diff erent crystallization conditions was investigated. The performed line chemical analysis of specimensproved creation of tantalum micro segregation, so-called growth striations, which showed themselves on concentrationproĀ les as periodically alternating areas with increased and decreased concentrations of tantalum. The existenceof these chemical inhomogeneities suggests that stationary conditions of the crystal growth were disturbedduring the zone melting, i.e. fl uctuations of microscopic rate of growth occurred due to convection in the melt. Thedetermined eff ective distribution coeffi cients of tantalum in molybdenum and tungsten approach to calculatedtheoretical values of the equilibrium distribution coeffi cient.
机译:研究了不同结晶条件下电子束流化区熔化过程中钼和钨单晶中钽的分布。对标本进行的线化学分析证明了钽微偏析的产生,即所谓的生长条纹,其在浓度曲线上显示为钽浓度升高和降低的周期性交替区域。这些化学不均匀性的存在表明,在区域熔化期间晶体生长的固定条件受到干扰,即,由于熔体中的对流,导致了微观生长速率的波动。确定了钽在钼和钨中的有效分布系数,以计算出平衡分布系数的理论值。

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