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Synthetic faujasite based on coal by-products for the treatment of acid mine drainage (AMD).

机译:基于煤副产品的合成八面沸石,用于酸性矿山排水(AMD)的处理。

摘要

Acid mine drainage (AMD) has long been a significant environmental problem associated to mining operations at the Parys Mountain copper-lead-zinc deposit of Anglesey (North Wales), a volcanogenic massive sulphide district of major metallogenic importance. AMD is a natural occurrence resultingudfrom the microbial oxidation of sulphide minerals, especially pyrite (FeS2), pyrite in presence of water and air, which produces polluted waters strongly acidic containing high concentrations of Fe, sulphateudand toxic metals. The treatment of AMD has traditionally been conducted by neutralization with lime or similar materials. However, liming is often temporary and produces secondary wastes, such as metal hydroxide sludges and gypsum, which are highly regulated and have costly disposal requirements. Several methods for AMD treatment have been developed, although adsorption being the preferred method for heavy metal removal due to its effectiveness. AMD remediation can beudvery costly and difficult, due to the high costs of activated carbon production and regeneration for water treatment. Therefore, alternative low-cost liming materials are constantly sought. Such adsorbents should be readily available, economically viable and easily regenerated. The aim of this study is to investigate the efficiency of synthetic faujasite obtained from coal by-products as adsorbent in removing heavy metals from AMD generated at the Parys Mountain copper-lead-zinc deposit.
机译:长期以来,酸性矿山排水(AMD)一直是与安格西(北威尔士)的帕里斯山铜铅锌矿床的采矿作业相关的重大环境问题,该矿山是重要成矿作用的火山成块大块硫化物区。 AMD是自然现象,是由于硫化物矿物,尤其是黄铁矿(FeS2),在水和空气中的黄铁矿的微生物氧化而产生的,会产生含有高浓度的Fe,硫酸盐和有毒金属的强酸性污染水。传统上,AMD的处理方法是用石灰或类似材料中和。然而,撒石灰通常是暂时的,会产生二次废物,例如金属氢氧化物污泥和石膏,这些废物受到严格管制并具有昂贵的处置要求。已经开发了几种用于AMD处理的方法,尽管吸附由于其有效性是重金属去除的优选方法。由于活性炭生产和水处理再生的高昂成本,AMD修复可能非常昂贵且困难。因此,一直在寻找替代的低成本石灰材料。此类吸附剂应易于获得,经济可行且易于再生。这项研究的目的是研究以煤副产品为吸附剂的合成八面沸石从帕里斯山铜铅锌矿床产生的AMD中去除重金属的效率。

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