In this work, a multi-functional nanoparticle (TiO2-KH570-DOPO) has been successfully synthesized through the attachment of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-methacryloxy propyl trimethoxyl silane on the surface of titanium dioxide (TiO2). Supercritical carbon dioxide was used as the solvent in order to increase the grafting level. The chemical structure of TiO2-KH570-DOPO was fully characterized using Fourier transform infrared spectra, thermogravimetric analysis and transmission electron microscopy. The modified TiO2 was incorporated into flexible polyurethane foam (FPUF). The fire performance of FPUF blends was evaluated using microscale combustion calorimetry. Peak heat release rate and total heat release values were reduced from 657.0 W/g and 28.9 kJ/g for neat FPUF sample to 519.2 W/g and 26.8 kJ/g of FPUF specimen containing 10 wt % of TiO2-KH570-DOPO. Analysis of thermal stability and the observation of char formation suggests that TiO2-KH570-DOPO is active in the condensed phase.
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