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Study on the Torque Rheological Behavior of Wood Flour/Chitosan/Polyvinyl Chloride Composites

机译:木粉/壳聚糖/聚氯乙烯复合材料的扭矩流变行为研究

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摘要

Torque rheological properties of wood flour/chitosan/PVC (WF/CS/PVC) compounds were measured by a torque rheometer using roller-style rotating blades at various setting temperatures (175 and 185 °C) and rotation speeds (30, 45, 60, and 75 rpm). The torque rheological parameters were calculated based on the Marquez model and Arrhenius equation. The torque rheological curves of WF/CS/PVC composites were similar to WF/PVC composites without chitosan. The classical Marquez model was verified to be suitable for both WF/PVC and WF/CS/PVC composites. Specifically, the activation energy (ΔE), n value, and range of C(n)m for the former and latter were 27.698 kJ•mol-1 and 29.237 kJ•mol-1, 0.382 and 0.381, and 4.415 to 5.749 N•m•sn and 4.652 to 6.079 N•m•sn, respectively. The rheological properties of WF/CS/PVC composites did not show a great qualitative enhancement compared to WF/PVC composites.
机译:通过在各种设定温度(175和185°C)(175和185°C)和转速(30,45,60,通过扭矩流变仪通过扭矩流变仪测量木粉/壳聚糖/ PVC(WF / CS / PVC)化合物的扭矩流变性能。滚动式旋转刀片(30,45,60和75 rpm)。基于Marquez模型和Arhenius方程计算扭矩流变参数。 WF / CS / PVC复合材料的扭矩流变曲线与没有壳聚糖的WF / PVC复合材料类似。经典的Marquez模型被验证适用于WF / PVC和WF / CS / PVC复合材料。具体地,前者和后者的活化能(ΔE),n值和C(n)m的范围为27.698kJ•mol-1和29.237kj•mol-1,0.382和0.381,4.415至5.749 n M•SN和4.652至6.079 N•M•Sn。与WF / PVC复合材料相比,WF / CS / PVC复合材料的流变性能没有显示出巨大的定性增强。

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