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A Simple Method of Preparation of High Silica Zeolite Y and Its Performance in the Catalytic Cracking of Cumene

机译:一种简单的制备高硅沸石Y的方法及其在催化开裂中的性能

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摘要

A series of high silicon zeolites Y were prepared through direct synthetic method by using silica sol as the silicon source and sodium aluminate as the aluminum source. The effects of alkalinity and crystallization time of the process of synthesis were investigated. To separately reveal the crystalline structure, element content, morphology, and surface areas, the as-synthesized zeolite Y was characterized by powder X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), and N2 adsorption-desorption isotherms (BET). The results show the as-synthesized zeolite Y with high relative crystallization and uniform morphology; the SiO2/Al2O3 ratio was about 4.54~6.46. For an application, the zeolite cracking activity was studied with cumene as the probe molecules.
机译:通过使用二氧化硅溶胶作为硅源和铝酸钠作为铝源,通过直接合成方法制备一系列高硅沸石Y。研究了合成过程的碱度和结晶时间的影响。分别揭示结晶结构,元素含量,形态和表面积,以合成的沸石Y以粉末X射线衍射(XRD),X射线荧光(XRF),扫描电子显微镜(SEM)为特征。 N2吸附 - 解吸等温线(BET)。结果表明,具有高相对结晶和均匀形态的合成沸石Y; SiO2 / Al2O3比率约为4.54〜6.46。对于施用,用异丙烯作为探针分子研究了沸石裂化活性。

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