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Characterisation of coal biomass mixture for co-gasifications

机译:用于牛气化的煤和生物质混合物的表征

摘要

Biomass fuels can be produce by widely available raw materials which is come from different sources and wide variety of forms. Co-gasification can reduce the cost of the feedstock and reduce the problems that occur in plant-operation due to the production of tar (Kumabe et al., 2006). For the pre-treatment of biomass, sample received were relatively dry for 24h under sunlight having less than 10 wt% moisture and were in the form of whole bunches. The EFB was manually chopped into small pieces. Then a grinder was used to reduce the size. For first analysis, heating value of EFB was determined by burning a weighed sample in an adiabatic oxygen-bomb calorimeter (model Parr 1341, USA). The apparent density of the EFB samples was determined using a gas pycnometer (model-. Micromeritics, AccuPyc II 1340) with helium as udpurging gas. The percentages of carbon, hydrogen, nitrogen, sulfur and oxygen (by difference) of the EFB sample were determined after complete combustion of the sample using a CHNS/O Analyzer (model LECO TruSpec CUN, USA) following the ASTM D-5291 method (Kezhong et al., 2009). The contents of moisture (dry basis), volatile matter, fixed carbon and ash were determined using a thermogravimetric analyzer (model Mettler Toledo, TGA/SDTA85 1, USA). One of the main objectives of this research is to study the effect on characteristic of mixture coal and biomass in co-gasification and compare with coal gasification or biomass gasification itself. For higher heating value, the average value is 24.5697 MJIkg. For apparent density of the mixture, as percentage of biomass increase, the apparent density also increased but after 70% biomass, the apparent--density starts-to reduced. For the proximate analysis, BO have 2 times greater weight loss compared to BlOO at the same temperature. For elemental analysis, B100 contains 2 times greater oxygen compared to BO but have greater carbon number compared to B100.Unlike coal, biomass with low ash and sulphur content, a high volatile matter yield and- fixed carbon with high reactivity could potentially be attractive from the economic, environmental and social points of view that poor coal. Low density and low calorific value of biomass causes an increase in the cost of transportation and storage, hence by co-gasification of biomass with coal is more economical compared to biomass alone.
机译:生物质燃料可以由来自不同来源和多种形式的广泛使用的原材料生产。共气化可以降低原料成本,并减少由于焦油的产生而在工厂运营中出现的问题(Kumabe等,2006)。为了对生物质进行预处理,将接收到的样品在日光下相对干燥24小时,水分含量少于10 wt%,并且为整束形式。 EFB手动切成小块。然后使用研磨机减小尺寸。对于首次分析,通过在绝热氧弹量热仪(型号Parr 1341,美国)中燃烧称重的样品来确定EFB的热值。 EFB样品的表观密度使用气体比重瓶(型号-Micromeritics,AccuPyc II 1340)以氦气作为吹扫气体确定。在样品完全燃烧后,使用CHNS / O分析仪(型号LECO TruSpec CUN,美国),按照ASTM D-5291方法确定EFB样品中碳,氢,氮,硫和氧的百分比(通过差异)( Kezhong等,2009)。使用热重分析仪(型号Mettler Toledo,TGA / SDTA85,美国)测定水分(干基),挥发性物质,固定碳和灰分的含量。本研究的主要目的之一是研究共气化过程中煤和生物质混合气对特性的影响,并与煤气化或生物质气化本身进行比较。对于更高的发热量,平均值为24.5697 MJIkg。对于混合物的表观密度,随着生物量百分比的增加,表观密度也随之增加,但是在70%的生物量之后,表观密度开始降低。为了进行近距离分析,与相同温度下的B100相比,BO的重量损失大2倍。对于元素分析,B100的氧含量是BO的2倍,但碳原子数却比B100大。与煤,低灰分和硫含量的生物质,高挥发性物质产率和高反应性的固定碳不同,B100具有潜在的吸引力。从经济,环境和社会的角度来看,贫煤。生物质的低密度和低热值导致运输和存储成本的增加,因此与单独的生物质相比,通过生物质与煤的共气化更加经济。

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    Nur Farah Hanim Rahmat;

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  • 年度 2014
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