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Study of the combined effects of oxidation and adsorption process in removing MTBE from wastewater

机译:氧化吸附法联合去除废水中MTBE的研究

摘要

Treatment of Methyl Tert-Butyl Ether (MTBE) from wastewater supplies presents specific challenges due to the physicochemical properties of MTBE which depend strongly on its hydrophilic nature, and translate into a high solubility in water. MTBE has very low Henry‘s constant and very low affinity for common adsorbents. An investigation was carried out for the treatability of metyl tert-butyl ether (MTBE) in synthetic wastewater. In this research, experimental rig and bench-scale studies using granular activated carbon (GAC) and hydrogen peroxide (H2O2) were conducted to observe the treatability of MTBE in synthetic wastewater. An experimental rig was built up that consist of three conjugated system. Subsequently, MTBE was amended to the H2O2 and air flow, followed by adsorption treatment with GAC. Generally, the major finding suggests that the longer cycle pulsation time (3 minutes open valve + 5 seconds closed valve) with air flow rate at 6 L/min over the synthetic wastewater caused a greater removal of MTBE. The result of this study can help to provide specific guidance into process parameter selection for treating MTBE in wastewaters. The optimum operating conditions are very important for treating the wastewater effectively in a larger scale.
机译:由于MTBE的物理化学特性强烈依赖于其亲水性,并转化为高水溶性,因此废水处理中的甲基叔丁基醚(MTBE)面临着特殊的挑战。 MTBE对常见吸附剂的亨利常数很低,并且亲和力很低。对甲基叔丁基醚(MTBE)在合成废水中的可处理性进行了研究。在这项研究中,进行了使用粒状活性炭(GAC)和过氧化氢(H2O2)的试验台和规模试验,以观察MTBE在合成废水中的可处理性。建立了由三个共轭系统组成的实验装置。随后,将MTBE修改为H2O2和气流,然后用GAC进行吸附处理。通常,主要发现表明,与合成废水相比,更长的循环脉动时间(打开阀3分钟+关闭阀5秒)和空气流速为6 L / min导致MTBE去除率更高。这项研究的结果可以为处理废水中MTBE的工艺参数选择提供具体指导。最佳的操作条件对于有效地大规模处理废水非常重要。

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    Teoh Tze Yang;

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  • 年度 2010
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